In more convenient units, ϵ g and , the expression of energy (10) can be written in a simpler form suitable for graphical representations: (11) where . For comparison (see (10)), in the case of a parabolic dispersion law (e.g., for QD consisting of GaAs), the total energy Bafilomycin A1 price in the strong SQ is given as [28]: (12) Weak size quantization regime In this regime, when the condition R 0 ≫ a p takes place, the system’s energy is caused mainly by the electron-positron Coulomb interaction.

In other words, we consider the motion of a Ps as a whole in a QD. In the case of the presence of Coulomb interaction between an electron and positron, the Klein-Gordon equation can be written as [41]: (13) where e is the elementary Combretastatin A4 molecular weight charge. After simple transformations, as in the case of a strong SQ regime, the Klein-Gordon equation reduces to the Schrödinger equation with a certain

effective energy, and then the wave function of the system can be represented as: (14) where . Here, describes the relative motion of the electron and positron, while describes the motion of the Ps center of gravity. After switching to the new coordinates, the Schrödinger equation takes the following form: (15) where is the mass of a Ps. One can derive the equation for a Ps center of gravity, 4-Aminobutyrate aminotransferase after www.selleckchem.com/products/mrt67307.html separation of

variables, in the and a p units: (16) or (17) where ϵ R is the energy of a Ps center of gravity quantized motion and L is the orbital quantum number of a Ps motion as a whole. For energy and wave functions of the electron-positron pair center of gravity motion, one can obtain, respectively, the following expressions: (18) (19) where N and M are, respectively, the principal and magnetic quantum numbers of a Ps motion as a whole. Further, let us consider the relative motion of the electron-positron pair. The wave function of the problem is sought in the form . After simple transformations, the radial part of the reduced Schrödinger equation can be written as: (20) where the following notations are introduced: . The change of variable transforms Equation 20 to: (21) where the parameter is introduced. When ξ → 0, the desired solution of (21) is sought in the form χ(ξ → 0) = χ 0 ~ ξ λ [45, 46]. Substituting this in Equation 21, one gets a quadratic equation with two solutions: (22) The solution satisfying the finiteness condition of the wave function is given as . When ξ → ∞, Equation 21 takes the form . The solution satisfying the standard conditions can be written as [45].